The aerospace industry demands strong, lightweight components of complex geometries for a variety of applications. Titanium alloys, e.g. Ti-6Al-4V, exhibit exceptional strength-to-weight ratio and corrosion resistance and are hence a top candidate for alloy selection. The recent emergence of additive manufacturing (AM) has mitigated the geometric constraints associated with more traditional casting methods and is already being used as a cost-effective solution for the manufacturing of complex parts, yet a better understanding of how build parameters influence the resulting microstructure is still required.
Steep thermal gradients and rapid cooling rates associated with laser-based AM lead to the formation of a completely martensitic microstructure [1-3] in Ti-6Al-4V. The resultant ductility is well below that required for critical structural applications [4]. Generally, electron beam melting (EBM) has allowed the formation of non-martensitic microstructures, namely an α+ β basket-wave structure, restoring ductility due to the intrinsic heat treatment associated with this process. However, martensite (α’) was reported in Ti-
Here, we report the direct observation of the martensitic alpha prime phase throughout EBM builds using a combination of microanalytical techniques including atom probe tomography (APT), transmission electron microscopy (TEM) and electron back-scattered diffraction (EBSD). Furthermore, alpha prime is shown to exist in builds larger in size, and therefore thermal mass, than that previously reported [5]. The findings provide valuable insights into the phase transformation behaviour during the rapid cooling and heating regimes of EBM.